Memoirs of the Faculty of Engineering, Okayama University
Published by Faculty of Enginerring, Okayama University

<Formerly known as>
Memoirs of the School of Engineering, Okayama University

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A Simple Model for Oxygen Conduction in Some Perovskite Compounds

Totsuji, Chieko
A simple model for oxygen ion conduction in perovskite compounds is proposed. The potential for an oxygen ion is calculated as the sum of the long range Coulomb potential and short range repulsive potential in a cubic lattice. The activation energy is estimated as the difference in the values of potential at the barrier and at the stable site. When appropriate conditions are satisfied, the activation energy has a minimum as a function of lattice constant in accordance with recent experiments.