Org_Lett_18_9_2110.pdf 450 KB
Takamura, Hiroyoshi Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University
Kikuchi, Takahiro Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University
Endo, Noriyuki Himeji EcoTech Co., Ltd.
Fukuda, Yuji Himeji EcoTech Co., Ltd.
Kadota, Isao Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University
The first total syntheses of sarcophytonolide H and the originally proposed and correct structures of isosarcophytonolide D have been achieved via transannular ring-closing metathesis (RCM). These total syntheses culminated in the stereostructural confirmation of sarcophytonolide H and the reassignment of isosarcophytonolide D, respectively. The antifouling activity of the synthetic sarcophytonolide H and its analogues was also evaluated.
This is an Accepted Manuscript of an article published by American Chemical Society
This work was supported by Okayama Foundation for Science and Technology and JSPS KAKENHI (24710250).
American Chemical Society
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