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ID 46904
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Title Alternative
酸化物ガラスの塩基度と XPS による O1s 化学シフトの相関に関する考察
Author
Miura, Yoshinari
Abstract
O1s binding energy measured by X-ray photoelectron spectroscopy (XPS) is candidate as a new tool to determine a new scale of Lewis basicity of oxide ions in glass. Some mathematical expressions for the basicity or XPS chemical shift, such as charge parameter and optical basicity, were compared with the experimental O1s binding energy in binary alkali oxide glasses. The expressions so far in use needed some modification in parameters. A new empirical expression introduced in this paper gives a new concept and universal scale of basicity.
Keywords
XPS
Basicity
Glass
O1s binding energy
Chemical shift
Published Date
2005-01
Publication Title
Journal of the Ceramic Society of Japan
Publication Title Alternative
日本セラミックス協会学術論文誌
Volume
volume113
Issue
issue1313
Publisher
The Ceramic Society of Japan
Publisher Alternative
公益社団法人日本セラミックス協会
Start Page
44
End Page
50
ISSN
0914-5400
NCID
AN10040326
Content Type
Journal Article
language
英語
Copyright Holders
Copyright (c) 2005 The Ceramic Society of Japan
File Version
publisher
Refereed
True
DOI