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ID 34211
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Author
Abe, Takashi
Uni, Miyuki
Yamamoto, Yoshinori
Abstract

Synthesis of the AB ring segments of ciguatoxin is described. The present synthesis includes a Lewis acid mediated cyclization of allylstannane with aldehyde, cross-metathesis reaction introducing the side chain, and Grieco-Nishizawa dehydration on the A ring.

Keywords
POLYCYCLIC ETHERS
ABSOLUTE-CONFIGURATION
HYDROXY GROUP
MOIETY
FRAGMENT
SYSTEM
ROUTE
CTX3C
Note
Published with permission from the copyright holder.
This is a author's copy,as published in Tetrahedron Letters , 2008 Vol.49 Issu.22 pp.3643-3647
Publisher URL: http://dx.doi.org/10.1016/j.tetlet.2008.03.145
Direct access to Thomson Web of Science record
Copyright © 2008 by Elsevier Ltd.
Published Date
2008-06-19
Publication Title
Tetrahedron Letters
Volume
volume49
Start Page
3643
End Page
3647
Content Type
Journal Article
language
英語
Refereed
True
DOI
Web of Sience KeyUT
Submission Path
organic_chemistry/4