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ID 57914
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Author
Iwasaki, Masayuki Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
Nonaka, Kosei Graduate School of Natural Science and Technology, Okayama University
Zou, Song
Sawanaka, Yuta Graduate School of Natural Science and Technology, Okayama University
Shinozaki, Takaaki Graduate School of Natural Science and Technology, Okayama University
Fujii, Tomoya Graduate School of Natural Science and Technology, Okayama University
Nakajima, Kiyohiko Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
Abstract
Copper-catalyzed regioselective aminothiolation of terminal and internal alkenes with N-fluorobenzenesulfonimide and thiols has been developed. The three-component reaction is promoted by the addition of dimethyl sulfide. In addition to aromatic alkenes, aliphatic alkenes are subjected to the reaction, affording various aminothiolation adducts as single regioisomers. The radical process is proposed by preliminary mechanistic studies, involving radical trap and radical clock experiments.
Published Date
2019-11-04
Publication Title
Journal of Organic Chemistry
Volume
volume84
Issue
issue23
Publisher
American Chemical Society
Start Page
15373
End Page
15379
ISSN
0022-3263
NCID
AA00704100
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
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author
PubMed ID
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1021/acs.joc.9b02392
Citation
J. Org. Chem. 2019, 84, 23, 15373-15379 Publication Date:November 7, 2019 https://doi.org/10.1021/acs.joc.9b02392
Funder Name
Japan Society for the Promotion of Science
助成番号
16K17901