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ID 58409
FullText URL
Author
Murai, Masahito Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Uemura, Erika Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko Division of Applied Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Abstract
Amines have been identified to greatly accelerate the intermolecular anti-Markovnikov addition of carbon nucleophiles to unactivated terminal alkynes. Using a combination of [ReBr(CO)3(thf)]2 and iPr2NEt, construction of cyclic all-carbon quaternary centers was achieved with various 1,3-ketoesters, diketones, and diesters with lower catalyst loading under milder conditions. The type of addition could be easily controlled by choice of additive, highlighting the unique features of rhenium catalysis
Keywords
rhenium
anti-Markovnikov addition
1,3-dicarbonyl compound
vinylidene
amine
Published Date
2018-05-04
Publication Title
ACS Catalysis
Volume
volume8
Issue
issue6
Publisher
American Chemical Society
Start Page
5454
End Page
5459
ISSN
2155-5435
NCID
AA12599706
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
DOI
Web of Science KeyUT
Related Url
isVersionOf http://dx.doi.org/10.1021/acscatal.8b01338
Funder Name
Ministry of Education, Culture, Sports, Science and Technology
助成番号
26248030