ID 58256
フルテキストURL
著者
Araki, Yuya Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Miyoshi, Natsumi Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Morimoto, Kazuki Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Kudoh, Takayuki Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University Kaken ID publons researchmap
Mizoguchi, Haruki Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID researchmap
Sakakura, Akira Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
抄録
A formal total synthesis of manzacidin B is described. beta,beta-Disubstituted gamma-hydroxy-beta-aminoalcohol, the key structure of manzacidin B, is stereoselectively constructed via sequential Henry reactions. By taking advantage of noncovalent interactions, such as intramolecular hydrogen bonding and chelation, we could diastereodivergently control the stereoselectivity of the Henry reaction.
備考
This document is the Accepted Manuscript version of a Published Work that appeared in final form inJournal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b02811.
発行日
2019-12-18
出版物タイトル
Journal of Organic Chemistry
85巻
2号
出版者
American Chemical Society
開始ページ
798
終了ページ
805
ISSN
0022-3263
NCID
AA00704100
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
論文のバージョン
author
PubMed ID
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1021/acs.joc.9b02811
ライセンス
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
Citation
J. Org. Chem. 2020, 85, 2, 798-805 Publication Date:December 18, 2019 https://doi.org/10.1021/acs.joc.9b02811
助成機関名
日本学術振興会
助成番号
18K0S123
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