ID 58409
フルテキストURL
著者
Murai, Masahito Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Uemura, Erika Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko Division of Applied Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
抄録
Amines have been identified to greatly accelerate the intermolecular anti-Markovnikov addition of carbon nucleophiles to unactivated terminal alkynes. Using a combination of [ReBr(CO)3(thf)]2 and iPr2NEt, construction of cyclic all-carbon quaternary centers was achieved with various 1,3-ketoesters, diketones, and diesters with lower catalyst loading under milder conditions. The type of addition could be easily controlled by choice of additive, highlighting the unique features of rhenium catalysis
キーワード
rhenium
anti-Markovnikov addition
1,3-dicarbonyl compound
vinylidene
amine
発行日
2018-05-04
出版物タイトル
ACS Catalysis
8巻
6号
出版者
American Chemical Society
開始ページ
5454
終了ページ
5459
ISSN
2155-5435
NCID
AA12599706
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
DOI
Web of Science KeyUT
関連URL
isVersionOf http://dx.doi.org/10.1021/acscatal.8b01338
助成機関名
文部科学省
助成番号
26248030
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