JaLCDOI 10.18926/fest/11442
フルテキストURL 011_099_101.pdf
著者 Uddin Md. Azhar| Tanihara Manbu| 武藤 明徳| 阪田 祐作|
抄録 Liquid phase oxidation of benzene to phenol was carried out with O(2) using carbon-based Fe-Pd and Cu-Pd catalysts at 40℃. The carbon-based Fe-Pd and Cu-Pd catalyst were prepared by modified carbothermal reduction of metal ion exchange method using cation exchange resin as a source of carbon. Fe/carbon, Cu/carbon and Pd/carbon were not effective for the oxidation of benzene to phenol with O(2) when H(2) was used as a catalyst reducing agent, however both Fe/carbon and Cu/carbon catalysts revealed activities when ascorbic acid was used as a reducing agent. Bimetallic catalysts such as Fe-Pd/carbon and Cu-Pd/carbon showed much higher activity for phenol production than the monometallic catalysts even when H(2) was used a reducing agent. Catalytic activity of Fe-Pd catalyst was much (ca. 2.5 times) higher than the Cu-Pd/catalyst. A physical mixture of the single component catalysts such as Fe and Pd or Cu and Pd were not effective in the oxidation of benzene to phenol, suggesting that an intimate contact between Fe or Cu species with Pd species is necessary to formulate an active catalyst.
キーワード oxidation of benzene synthesis of phenol metal-carbon catalyst
出版物タイトル 岡山大学環境理工学部研究報告
発行日 2006-03-15
開始ページ 99
終了ページ 101
ISSN 1341-9099
言語 English
論文のバージョン publisher
NAID 120002313983