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ID 34211
フルテキストURL
著者
Kadota, Isao Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University
Abe, Takashi Department of Chemistry, Graduate School of Science, Tohoku University
Uni, Miyuki Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University
Takamura, Hiroyoshi Department of Chemistry, Graduate School of Natural Science and Technology, Okayama University
Yamamoto, Yoshinori Department of Chemistry, Graduate School of Science, Tohoku University
抄録

Synthesis of the AB ring segments of ciguatoxin is described. The present synthesis includes a Lewis acid mediated cyclization of allylstannane with aldehyde, cross-metathesis reaction introducing the side chain, and Grieco-Nishizawa dehydration on the A ring.

キーワード
POLYCYCLIC ETHERS
ABSOLUTE-CONFIGURATION
HYDROXY GROUP
MOIETY
FRAGMENT
SYSTEM
ROUTE
CTX3C
備考
Published with permission from the copyright holder.
This is a author's copy,as published in Tetrahedron Letters , 2008 Vol.49 Issu.22 pp.3643-3647
Publisher URL: http://dx.doi.org/10.1016/j.tetlet.2008.03.145
Direct access to Thomson Web of Science record
Copyright © 2008 by Elsevier Ltd.
発行日
2008-06-19
出版物タイトル
Tetrahedron Letters
49巻
開始ページ
3643
終了ページ
3647
資料タイプ
学術雑誌論文
言語
English
査読
有り
DOI
Web of Sience KeyUT
Submission Path
organic_chemistry/4