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ID 11482
JaLCDOI
Sort Key
14
フルテキストURL
著者
Cassidy Patrick E. Institute for Environmental and Industrial Science, Texas State University at San Marcos
Fitch John W Institute for Environmental and Industrial Science, Texas State University at San Marcos
Venumbaka Sreenu R. Institute for Environmental and Industrial Science, Texas State University at San Marcos
抄録
Fluorine-containing poly(ether ketone)s was synthesized by the nucleophilic aromatic substitution reaction of 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 4,4'-bis(2,3,4,5,6-pentafluorobenzoyl) diphenyl ether in super-critical CO(2). Polymerizations were carried out at 80℃ for 6 hours under 5000 psi of CO(2) pressure, which was super-critical phase. Polymerization concentration was 0.5 g of polymer in 10 - 12 mL of CO(2). The polymer was not obtained in CO(2) due to the insolubility of both the potassium bisphenoxide and the polymer into CO(2). However, the polymer was formed by an addition of DMAc and NMP in CO(2), even though molecular weight was not so high. Very small amount of co-solvents which were immiscible with CO(2) was effective, and it was 1/20 - 1/25 amount of the solvent used in the conventional poly(ether ketone) synthesis. The polymerization mechanism was also discussed.
キーワード
super-critical carbon dioxide
plastics
high performance
environmentally benign
出版物タイトル
岡山大学環境理工学部研究報告
発行日
2006-03-15
11巻
1号
出版者
岡山大学環境理工学部
出版者(別表記)
Faculty of Environmental Science and Technology, Okayama University
開始ページ
93
終了ページ
97
ISSN
1341-9099
NCID
AN10529213
資料タイプ
紀要論文
OAI-PMH Set
岡山大学
言語
English
論文のバージョン
publisher
NAID
Eprints Journal Name
fest