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ID 58546
フルテキストURL
著者
Murai, Masahito Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Takai, Kazuhiko Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
抄録
A rhenium complex catalyzed the formation of 2-iodo-1H-indene derivatives through iodine and hydrogen migration of 3-iodopropargyl ethers. The reaction proceeded via generation of 1-iodoalkenylrhenium carbene species by sequential 1,2-iodine and 1,5-hydrogen shifts with readily available precursors under neutral conditions. The reaction mechanism and the reactivity of the generated alkenylcarbene species were also investigated.
キーワード
anti-markovnikov addition
silyl enol ethers
terminal alkynes
metal vinylidenes
cycloisomerization
ruthenium
complexes
derivatives
carbene
functionalization
発行日
2019-08-08
出版物タイトル
Organic Letters
21巻
17号
出版者
American Chemical Society
開始ページ
6756
終了ページ
6760
ISSN
15237060
NCID
AA11347843
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
論文のバージョン
author
PubMed ID
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1021/acs.orglett.9b02380
助成機関名
文部科学省
助成番号
18H03911
19H02719