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ID 58755
著者
Fu, Liyan Graduate School of Natural Science and Technology, Okayama University
Chen, Qiang Graduate School of Natural Science and Technology, Okayama University
Wang, Zhenhua Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
抄録
Palladium-catalyzed decarbonylative alkylation reactions of acyl fluorides have been developed using alkylboranes having β-hydrogens. A wide range of functional groups were well tolerated, even at the high temperature required for decarbonylation. This protocol provides a diverse C(sp2)–C(sp3) bond formation via a highly efficient decarbonylative process. The hemilabile bidentate ligand DPPE plays a crucial role for retardation of the undesired β-hydride elimination.
備考
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Organic Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c00542.
This fulltext is available in May 2021.
発行日
2020-05-05
出版物タイトル
Organic Letters
22巻
6号
出版者
American Chemical Society
開始ページ
2350
終了ページ
2353
ISSN
15237060
NCID
AA11347843
資料タイプ
学術雑誌論文
言語
English
論文のバージョン
author
PubMed ID
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1021/acs.orglett.0c00542